常兴华

副教授 硕士生导师

入职时间:2018-08-31

所在单位:资源加工与生物工程学院

职务:副系主任

学历:博士研究生毕业

性别:男

学位:博士学位

在职信息:在职

毕业院校:北京大学

曾获荣誉:

2023-11-01  当选:  中南大学教学质量优秀奖

2023-05-04  当选:  中南大学2021-2023年优秀共产党员

2022-01-02  当选:  中南大学教学质量优秀奖

2022-01-02  当选:  中南大学创新创业教育类教学质量优秀奖

2021-06-02  当选:  中南大学首届“课程思政三十佳”奖

2020-08-14  当选:  湖南省创新创业大赛三等奖

   
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Engineering metal sulfides with hierarchical interfaces for advanced sodium-ion storage systems

发布时间:2020-05-23

点击次数:

影响因子:10.733

DOI码:10.1039/c9ta13899d

所属单位:Cent S Univ

发表刊物:J. Mater. Chem. A

摘要:Antimony sulfide as an energy storage material with remarkable theoretical capacity has captured the attention of several researchers, but it has disadvantages such as volume expansion, polysulfide dissolution, and sluggish kinetics. By utilizing the oxygen functional groups in phenolic resin, engineering the nature mineral Sb2S3 with hierarchical interfaces (Sb, S-doped carbon) can be undertaken, effectively facilitating the diffusion of ions and accommodating volume changes. Importantly, the double-controlling synergistic effects of the Sb shell and S-doped carbon would prolong the diffusion pathway of polysulfides, considerably enhancing the sodium-ion storage capability. As a result, a capacity retention rate of 97.1% at 0.1 A g(-1) could be obtained after 200 cycles. At 0.5, 1.0, and 2.0 A g(-1) after 150 cycles, capacities of 422.6, 367, and 311.1 mA h g(-1), respectively, could be retained. A detailed investigation regarding capacity confirmed that the introduced hierarchical interfaces could significantly promote the faster transfer of electrons and trapping of polysulfides accompanied with improved reversible conversion reactions. The quantitative analyses of capacitive contribution and EIS data revealed that the core-shell structure and S-doped carbon could fundamentally boost the pseudocapacitive behaviors with improved transfer of electrons/ions. This rational design is expected to brighten the prospects for designing metal sulfides for use as advanced anodes in sodium-ion batteries.

合写作者:Xiaobo, Ji, Wei*, Sun, Yue, 刘洋, Xinghua, Chang, Feng, Jiang, Limin, Zhang

第一作者:Wenqing, Zhao

论文类型:期刊论文

通讯作者:Wei*, Sun

一级学科:0805 材料科学与工程

文献类型:J

是否译文:

发表时间:2020-03-01

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