• 教师名称:刘广义( 教授 、博士生导师 )
  • 学位:博士学位
  • 学科:化学工程与技术
  • 学历:博士研究生毕业
  • 单位:化学化工学院
  • 获得荣誉:全国优秀博士论文,教育部新世纪优秀人才,国家技术发明二等奖(排名第二),陈国达教育基金,湖南省石油化工优秀工程师



个人简介
刘广义,男,1974年-,博士,教授,博士生导师,化学化工学院副院长。
全国优秀博士论文获得者,教育部“新世纪优秀人才”,湖南省青年骨干教师,中南大学首届“升华育英”人才,湖南省石油化工优秀工程师。
获国家技术发明二等奖1项,省部级科技进步一等奖、二等奖4项,SCI论文90余篇,EI论文20余篇,授权中国发明专利50余项。
主持国家自然科学基金3项,“973”、“863”、 “十一五”支撑子课题各1项,全国优博作者专项基金、“新世纪优秀人才支持计划”基金、中南大学升华育英计划和创新驱动计划各1项,校企合作项目10多项。参加“863”、“973”、国家自然科学基金及校企合作项目50余项。多项专利技术产业化、商业化。
教育经历
  • [1]   1992.9-1996.7
     吉首大学  |  化学  | 学士学位   |  大学本科毕业

  • [2]   1996.9-1999.7
     中南大学  |  矿物加工工程  | 硕士学位   |  硕士研究生毕业

  • [3]   1999.9-2004.11
     中南大学  |  矿业工程  | 博士学位   |  博士研究生毕业

工作经历
  • [1]   1999.7-至今
     化学化工学院 |  中南大学 |  教授 |  教师 |

  • [2]   2010.6-2014.8
     化工与材料系 |  University of Alberta |  Visiting professor/Visiting scholar |

团队成员
表面与界面

暂无介绍

 研究概况

1. 界面与表面

2. 功能有机分子/表面活性剂合成及设计
3. 表面工程
4. 精细有机化工
5. 光、电材料


课题组研究生:毕业硕士研究生21名、博士研究生2名;在读硕士研究生7名、博士研究生8名。
主讲课程:化学工艺学,化工热力学,精细化工导论

招生学科:化学工艺,化学工程,应用化学。

欢迎化工、化学、物理和矿物加工专业的学生报考研究生。



第一/通讯作者论文(部分)


1.  Novel chelating surfactant 5-heptyl-1,2,4-triazole-3-thione: Its synthesis and flotation separation of malachite against quartz and calcite. Minerals Engineering. 2018.

2.  A DFT prediction on the chemical reactivity of novel azolethione derivatives as chelating agents Implications for copper minerals flotation and copper corrosion inhibition. Journal of the Taiwan Institute of Chemical Engineers. 2018.

3.  Thiadiazole-thione surfactants Preparation, flotation performance and adsorption mechanism to malachite. Journal of Industrial and Engineering Chemistry. 2018.

4.  5-Heptyl-1,3,4-oxadiazole-2-thione: Synthesis and flotation mechanism to chalcopyrite. Journal of Industrial and Engineering Chemistry. 2018.

5.  Cu(I)/Cu(II) mixed-valence surface complexes of S- (2-hydroxyamino)-2-oxoethyl -N,N-dibutyldithiocarbamate: Hydrophobic mechanism to malachite flotation. Journal of Colloid and Interface Science. 2018.

6.  Hemimorphite Flotation with 1-hydroxydodecylidene-1,1-diphosphonic acid and Its Mechanism. Minerals.2018.

7.  New advances in the understanding and development of flotation collectors: A Chinese experience. Minerals Engineering. 2018.

8.  Structure-activity relationship of xanthates with different hydrophobic groups in the flotation of pyrite. Minerals Engineering. 2018.

9.  The hydrophobic mechanism of di(2-ethylhexyl) phosphoric acid to hemimorphite flotation.Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2018.

10.  A DFT study on the structure-reactivity relationship of aliphatic oxime derivatives as copper chelating agents and malachite flotation collectors. Journal of Industrial and Engineering Chemistry. 2017.

11.  Molecular design of flotation collectors: A recent progress. Advances in Colloid and Interface Science. 2017.

12.  Synthesis and structural characterization of silver(I) and gold(I) complexes of N,N '-diisobutyloxycarbonyl-N '',N '''-(1,3-propylene)-bisthiourea. Polyhedron. 2017.

13.  The adsorption mechanism of N-butoxypropyl-S- 2-(hydroxyimino) propyl dithiocarbamate ester to copper minerals flotation. International Journal of Mineral Processing. 2017.

14.  The flotation behavior and adsorption mechanism of O-isopropyl-S- 2-(hydroxyimino) propyl dithiocarbonate ester to chalcopyrite. Journal of the Taiwan Institute of Chemical Engineers.2017.

15.  The role of HABTC's hydroxamate and dithiocarbamate groups in chalcopyrite flotation.Journal of Industrial and Engineering Chemistry. 2017.

16.  A novel surfactant 2-amino-6-decanamidohexanoic acid: Flotation performance and adsorption mechanism to diaspore. Minerals Engineering. 2016.

17.  A novel surfactant, N,N-diethyl-N'-cyclohexylthiourea: Synthesis, flotation and adsorption on chalcopyrite. Journal of Industrial and Engineering Chemistry. 2016.

18.  Adsorption of alpha-hydroxyoctyl phosphonic acid to ilmenite/water interface and its application in flotation. Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2016.

19.  In situ probing the self-assembly of 3-hexyl-4-amino-1,2,4-triazole-5-thione on chalcopyrite surfaces. Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2016.

20.  Investigation on the flotation behavior and adsorption mechanism of 3-hexyl-4-amino-1,2,4-triazole-5-thione to chalcopyrite. Minerals Engineering. 2016.

21.  Investigation on the selectivity of N-((hydroxyamino)-alkyl) alkylamide surfactants for scheelite/calcite flotation separation. Journal of Industrial and Engineering Chemistry. 2016.

22.  The activation mechanism of Cu(II) to ilmenite and subsequent flotation response to alpha-hydroxyoctyl phosphinic acid. Journal of Industrial and Engineering Chemistry. 2016.

23.  Understanding the hydrophobic mechanism of 3-hexyl-4-amino-1, 2,4-triazole-5-thione to malachite by ToF-SIMS, XPS, FTIR, contact angle, zeta potential and micro-flotation. Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2016.

24.  A novel surfactant N-(6-(hydroxyamino)-6-oxohexyl)octanamide: Synthesis and flotation mechanisms to wolframite. Separation and Purification Technology. 2015.

25.  Adsorption thermodynamics and kinetics of N, N'-diisopropoxypropyl-N", N'''-oxydiethylenedicarbonyl bis (thiourea) on chalcopyrite surfaces. Journal of Industrial and Engineering Chemistry. 2015.

26.  Flotation behavior and adsorption mechanism of alpha-hydroxyoctyl phosphinic acid to malachite. Minerals Engineering. 2015.

27.  Flotation performances and adsorption mechanism of alpha-hydroxyoctyl phosphinic acid to cassiterite. Applied Surface Science. 2015.

28.  N-(6-(hydroxyamino)-6-oxohexyl) decanamide collector: Flotation performance and adsorption mechanism to diaspore. Applied Surface Science. 2015.

29.  A novel collector 2-ethyl-2-hexenoic hydroxamic acid: Flotation performance and adsorption mechanism to ilmenite. Applied Surface Science. 2015.

30.  Study of N-isopropoxypropyl-N'-ethoxycarbonyl thiourea adsorption on chalcopyrite using in situ SECM, ToF-SIMS and XPS. Journal of Colloid and Interface Science. 2015.

31.  Gemini trisiloxane surfactant: Synthesis and flotation of aluminosilicate minerals. Minerals Engineering. 2014.

32.  Investigations on reverse cationic flotation of iron ore by using a Gemini surfactant: Ethane-1,2-bis(dimethyl-dodecyl-ammonium bromide). Chemical Engineering Journal. 2014.

33.  Synthesis, characterization and properties of 3,3'-diethyl-1,1'-oxydiethylenedicarbonyl bis(thiourea). Research on Chemical Intermediates. 2014.

34.  The interaction of N-butoxypropyl-N'-ethoxycarbonylthiourea with sulfide minerals: Scanning electrochemical microscopy, diffuse reflectance infrared Fourier transform spectroscopy, and thermodynamics. Colloids and Surfaces a-Physicochemical and Engineering Aspects. 2014



部分授权发明专利

(1) 刘广义,麻龙群,黄耀国,钟宏. 一种1,3,4-噁二唑-2-硫酮类浮选捕收剂的应用,ZL201610846837.72018-04-03.

(2) 刘广义,刘俊,胡哲. 一种1,2,4,5-四唑-3-硫酮类浮选捕收剂的应用,ZL201610846730.22018-05-11.

(3) 刘广义,黄耀国. 黄原酸盐的制备方法,ZL201510906094.32018-02-27.

(4) 刘广义,黄耀国,麻龙群. 一种134-噻二唑-2-硫酮类浮选捕收剂的应用,ZL201610846832.42018-07-17.

(5) 刘广义,肖静晶,王勇泉,钟宏,王帅,曹占芳,一种双配体捕收剂及其制备和应用,ZL201210570221.32014-04-02

(6) 刘广义,钟宏,狄宁,一种硫脲化合物及其在金属矿浮选中的应用和制备,ZL201110341679.72013-10-23

(7) 刘广义,钟宏,曹占芳,喻名强,一种硫脲化合物及制备和其在金属矿浮选中的应用,ZL201110341407.72014-11-05

(8) 刘广义,刘胜,黄耀国. 一种具有巯基-异羟肟酸基结构的有色金属矿浮选捕收剂及其制备方法和应用ZL201510202506.52017-03-01.

(9) 刘广义,曲肖彦,钟宏,刘胜,王帅,曹占芳. 一种氨基三唑类硫酮捕收剂的应用ZL201410576691.X2017-03-15.

(10) 刘广义,肖静晶,杨湘琳,钟宏. 一种具有巯基-肟基结构的有色金属矿浮选捕收剂及其应用, ZL201510201017.82017-04-19.

(11) 刘广义,张惠丽,钟宏,刘胜,赵刚,肖静晶,一种异羟肟酸或异羟肟酸盐的制备方法,ZL201410189143.12015-07-01



研究方向
  • [1]  1. 界面与表面
    涉及表面光电催化,表面电化学,单分子层自组装、表面处理、界面重构、界面吸附与溶出、表面改性等基础研究及其表征和第一性原理计算。
    2. 功能有机分子/表面活性剂合成及设计
    功能有机分子的结构-活性-毒性关系及其制备与应用新技术。
    3. 表面工程
    a. 采用高效浮选药剂实现金属矿和非金属矿资源的高效开发利用;b. 选冶联合短流程;c. 金属表面处理。
    4. 精细有机化工
    精细有机化学品的合成工艺及其产业化技术。
    5. 光、电材料
    材料制备、电化学、光化学、催化性能。

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