Sex:Male
Date of Birth:1992-11-04
Alma Mater:清华大学
Education Level:With Certificate of Graduation for Doctorate Study
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刘涵子,动力工程及工程热物理专业,工学博士,硕士研究生导师。
主要从事能源领域的非均相催化理论与应用研究,包括CO2捕集与原位电/热转化、能源清洁转化利用、吸附-催化双功能材料开发、固体废弃物资源化利用等。主持国家重点研发计划项目子课题1项、国家自然科学基金项目1项、湖南省自然科学基金1项,参与清华-华能基础能源联合研究院工程转化示范项目等。
研究概况
1、针对当前CO2捕集、利用与封存技术受高能耗、高成本等问题制约,研究集成CO2捕集和利用(ICCU)技术利用双功能材料(DFMs),实现等温条件下的燃煤烟气中CO2吸附及原位转化,消除CO2捕集后的运输和储存环节,降低整体技术工艺成本。2、在能源、化工、冶金等领域,由于工艺设计以及运行调整,应用选择性非催化还原(SNCR)技术的污染控制装置或反应区烟气温度低于最佳窗口,导致脱硝效率低及氨逃逸防治困难。针对燃煤烟气NOx脱除过程所涉及的NH3非定向氧化等科学问题,采用第一性原理展开机理研究,建立表面多组分反应动力学模型,考察气固流动与扩散对反应的影响,研发成果试验于2t/h综合中试平台(自研)及多台300MW级燃煤循环流化床锅炉等燃烧装置中,形成工业应用方案,并依托国家重点研发计划项目推进示范及转化。
清洁低碳能源技术创新团队科研方向丰富,可指导能源、环境和化工专业本科生、研究生开展实验、理论计算、各类科研及学科竞赛并提供优质资源,推荐交流深造,欢迎联系:liuhz@csu.edu.cn,能源楼105办公室。
本科教学
《自动控制原理》专业课
1. 一种城市湿垃圾沼气与干垃圾烟气协同制合成气的方法及系统,第十七届全国大学生节能减排竞赛一等奖,2024。
2. 中南大学大学生创新创业训练项目,国家级立项,2024。
3. 基于热化学CO2化学链的碳氢联合循环利用的方法及装置,第十六届全国大学生节能减排竞赛二等奖,2023。
4. 中南大学大学生创新创业训练项目,国家级立项,2023。
5. 钙基双功能材料原位吸附CO2与加氢性能研究,曹荣昌,优秀本科毕业设计,2024。
6. Rongchang Cao, et al. Carbon Capture Science & Technology. 2024, 13, 100275.
7. 一种用于碳、氢联合循环利用的方法和装置,国家发明专利,曹荣昌等,专利号:202211578960.7,2023。
科研项目
国家重点研发计划“煤炭清洁高效利用技术”专项子课题,2025-2029,主持,在研
国家自然科学基金青年科学基金项目,2024-2027,主持,在研
湖南省普通本科高校教学改革研究项目(重点),2024-2026,主持,在研
湖南省自然科学基金青年科学基金项目,2024-2027,主持,在研
国家重点研发计划“工业锅炉节能及清洁燃烧”课题,参与,结题
清华-华能基础能源联合研究院“担载型添加剂提升CFB锅炉低负荷SNCR脱硝氨利用率技术”工程转化示范项目,参与,结题
学术论文
2024-:
1. Rongchang Cao, Lei Liu, Hanzi Liu*, Zhiqiang Sun*. Suppressing cyclic deactivation of magnesium-calcium dual-functional materials via dispersed metal-carbonate interfaces for integrated CO2 capture and conversion. Carbon Capture Science & Technology. 2024, 13, 100275.
2. Hanzi Liu, Ling Cen, Xinlin Xie, Lei Liu, Zhao Sun, Zhiqiang Sun*.Engineering nanoparticle structure at synergistic Ru-Na interface for integrated CO2 capture and hydrogenation. Journal of Energy Chemistry. 2025, 100, 779-791.
3. Xinlin Xie, Lei Liu, Hanzi Liu*, Zhiqiang Sun*. Mechanistic insights into SO2-induced deactivation of Ni-based materials for integrated CO2 capture and methanation. Fuel. 2025, 382, 133755.
-2024:
1. Liu, H.; You, C.; Wang, H., Experimental and Density Functional Theory Studies on the Zeolite-Based Fe–Ni–W Trimetallic Catalyst for High-Temperature NOx Selective Catalytic Reduction: Identification of Active Sites Suppressing Ammonia Over-oxidation. ACS Catalysis. 2021, 11, 1189-1201.
2. Liu, H.; Zhang, Y.; Wang, H.; You, C., Performance of Fe-Ni-W exchanged zeolite for NOx reduction with NH3 in a lab-scale circulating fluidized bed. Fuel. 2022, 307, 121807.
3. Liu, H.; You, C.; Wang, H., Time-resolved in-situ IR and DFT study: NH3 adsorption and redox cycle of acid site on vanadium-based catalysts for NO abatement via selective catalytic reduction. Chemical Engineering Journal. 2020, 382, 122756.
4. Liu, H.; Chen, Z.; Wang, H.; You, C., Active centers response to SO2 and H2O poisoning over Fe-W-Ni exchanged zeolite for high-temperature NH3-SCR: Experimental and DFT Studies. Applied Surface Science. 2021, 570, 151105.
5. Liu, H.; Zhao, S.; You, C.; Wang, H., Experimental Study of the Enhancement of the Selective Noncatalytic Reduction Denitrification Process with Methane and Propane in a Circulating Fluidized Bed. Industrial & Engineering Chemistry Research. 2019, 58, 7825-7833.
6. Wang, T.; Liu, H.*; Sun, B., Catalytic conversion of NO assisted by plasma over Mn-Ce/ZSM5-multi-walled carbon nanotubes composites: Investigation of acidity, activity and stability of catalyst in the synergic system. Applied Surface Science. 2018, 457, 187-199.
7. Liu, H.; Wang, T.; Sun, B., Influence of the TiO2/multi-walled carbon nanotubes (MWCNTs) mass ratio on NO removal over the Mn/TiO2(x)-MWCNTs(1−x) catalyst assisted by plasma. Reaction Kinetics Mechanisms and Catalysis. 2017, 121, 735-749.
8. 刘涵子,王海名,由长福. 铁基分子筛高温NH3-SCR反应性能及机理研究. 工程热物理学报. 2022.
9. Wang, H.; Liu, H.; Chen, Z.; You, C., Interaction between SO2 and NO in their adsorption and photocatalytic conversion on TiO2, Chemosphere. 2020, 249, 126136.
10. Wang, T.; Liu, H.; Sun, B., A plasma-assisted catalytic system for NO removal over CuCe/ZSM-5 catalysts at ambient temperature, Fuel Process. Technol. 2017, 158, 199-205.
11. Wang, T.; Liu, H.; Sun, B., NO and SO2 Removal using Dielectric Barrier Discharge Plasma at Different Temperatures. J. Chem. Eng. Jpn. 2017, 50, 702-709.
12. Wang, T.; Liu, H.; Sun, B., Effect of plasma-catalyst system on NO removal using M–Cu (M = Mn, Ce, Cr, Co, and Fe) catalysts. Jpn. J. Appl. Phys., 2016, 55, 116202.
13. Wang, T.; Zhang, X.; Liu, H.; Sun, B., A comparison of NO reduction over Mn–Cu/ZSM5 and Mn–Cu/MWCNTs catalysts assisted by plasma at ambient temperature. Catal. Surv. Asia, 2017, 21, 94-102.
14. Chen, Z.; You, C.; Liu, H.; Wang, H., The synergetic particles collection in three different wet flue gas desulfurization towers: A pilot-scale experimental investigation, Fuel Process. Technol. 2018, 179, 344-350.
15. Wang, T.; Zhang, X.; Liu, J.; Liu, H.; Sun, B., Comparison of NO conversion over Cu/M (M = TiO2, Al2O3, ZSM-5, carbon nanotubes, activated carbon) catalysts assisted by plasma, React. Kinet. Mech. Cat., 2018, 124, 587-601.
16. Wang, T.; Zhang, X.; Liu, J.; Liu, H.; Sun, B., Effects of temperature on NOx removal with Mn-Cu/ZSM5 catalysts assisted by plasma. Appl. Therm. Eng. 2018, 130, 1224-1232.
17. Wang, T.; Zhang, X.; Liu, J.; Liu, H.; Sun, B., Plasma-assisted catalytic conversion of NO over Cu-Fe catalysts supported on ZSM-5 and carbon nanotubes at low temperature, Fuel Process. Technol., 2018, 178, 53-61.
18. Dai, X.; Zhou, X.; Liu, H.; Wang, T.; Zhang, Y.; Zhang, H.; Sun, B., Molecular-level insights into the immobilization of vapor-phase mercury on Fe/Co/Ni-doped hierarchical molybdenum selenide. Journal of Hazardous Materials 2021, 420, 126583.
19. Gu, S.; Yang, Z.; Chen, Z.; Wang, H.; Liu, H.; Zhang, W.; You, C., Insights into the desulfurization mechanism of low-grade limestone as absorbent induced by particle size. Fuel 2021, 305, 121444.
教育经历
1. 2018.09~2022.06
清华大学 | 动力工程及工程热物理 | 工学博士
2. 2015.09~2018.03
华北电力大学(北京) | 热能工程 | 工学硕士
3. 2011.09~2015.06
华北电力大学(北京) | 热能与动力工程 | 工学学士
专利成果
1. 刘涵子, 由长福. 一种用于中高温脱硝的铁基催化剂及其制备方法和应用. 发明专利. 201910523584.3.
2. 刘涵子, 由长福. 一种SNCR增效剂制备方法和应用. 发明专利. 202111020701.8.
3. 由长福, 刘涵子. 一种500-900度脱硝增效方法. 发明专利, 202011081409.2.
4. 由长福, 刘涵子. 一种循环流化床锅炉脱硝增效添加剂制备方法. 发明专利. 202011106373.9.
5. 王海名,刘涵子,由长福. 一种水泥窑装置和SNCR脱硝方法. 发明专利. 202110191347.9.
学术兼职
《Atmosphere》期刊 Guest Editor
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