刘涵子，动力工程及工程热物理专业，工学博士，硕士研究生导师。湖南省芙蓉计划人才项目获得者。

主要研究燃煤清洁高效利用、CO₂捕集与热（电）转化一体化、气固催化大模型等。主持国家重点研发计划项目子课题1项、国家自然科学基金项目1项、河北省自然科学重大项目课题1项、湖南省自然科学青年基金（B类）1项、湖南省自然科学青年基金（C类）1项，参与清华-华能基础能源联合研究院工程转化示范项目等。

研究概况

1、针对当前CO₂捕集、利用与封存技术受高能耗、高成本等问题制约，研究集成CO2捕集和利用（ICCU）技术利用双功能材料（DFMs），实现等温条件下的燃煤烟气中CO2吸附及原位转化，消除CO2捕集后的运输和储存环节，降低整体技术工艺成本。2、在能源、化工、冶金等领域，由于工艺设计以及运行调整，应用选择性非催化还原（SNCR）技术的污染控制装置或反应区烟气温度低于最佳窗口，导致脱硝效率低及氨逃逸防治困难。针对燃煤烟气NOx脱除过程所涉及的NH₃非定向氧化等科学问题，采用第一性原理展开机理研究，建立表面多组分反应动力学模型，考察气固流动与扩散对反应的影响，研发成果试验于2t/h综合中试平台及多台300MW级燃煤循环流化床锅炉等燃烧装置中，形成工业应用方案，并依托国家重点研发计划项目推进示范及转化。

欢迎2026年推免、考研本科生联系。清洁低碳能源团队具有应用及学术性课题方向，可根据学生就业或深造需求设计。本人指导本科、研究生开展实验、计算等科研及竞赛。提供优质办公条件、补助、灵活时间、针对性讨论。定期参与学术会议报告，产出成果按比例奖励，可推荐至清华大学等密切合作院校交流、合作和深造。liuhz@csu.edu.cn，能源楼105办公室。

本科教学&培养

《自动控制原理》专业课

1. 一种城市湿垃圾沼气与干垃圾烟气协同制合成气的方法及系统，第十七届全国大学生节能减排竞赛一等奖，2024-2025。

2. 中南大学大学生创新创业训练项目，国家级立项，2024-2025。

3. 基于热化学CO₂化学链的碳氢联合循环利用的方法及装置，第十六届全国大学生节能减排竞赛二等奖，2023-2024。

4. 中南大学大学生创新创业训练项目，国家级立项，2023-2024。

5. 钙基双功能材料原位吸附CO₂与加氢性能研究，曹荣昌，优秀本科毕业设计，2024。

6. Rongchang Cao, et al. Carbon Capture Science & Technology. 2024, 13, 100275. 

7. 一种用于碳、氢联合循环利用的方法和装置，国家发明专利，曹荣昌等，专利号：202211578960.7，2023。

曹荣昌（推免至上交）、郭康（推免至清华）

科研相关项目

国家重点研发计划“煤炭清洁高效利用技术”专项子课题，2025-2029，主持，在研

国家自然科学基金青年科学基金项目，2024-2027，主持，在研

河北省自然科学重大项目-燕赵电力实验室联合基金课题（工程示范），2026-2028，主持，在研

湖南省自然科学基金青年基金项目（B类），2026-2028，主持，在研

湖南省普通本科高校教学改革研究项目（重点），2024-2026，主持，在研

湖南省自然科学基金青年基金项目（C类），2024-2027，主持，在研

国家重点研发计划“工业锅炉节能及清洁燃烧”课题，参与，结题

清华-华能基础能源联合研究院“担载型添加剂提升CFB锅炉低负荷SNCR脱硝氨利用率技术”工程转化示范项目，参与，结题

学术论文

2026年

1. Xie X, Yuan J, Liu L, Liu H*, Sun Z*. Dual kinetic effect from confined iron nanoparticles in zeolite modulates high-temperature catalytic NO reduction and NH3 oxidation[J]. Industrial Chemistry & Materials. 2026. (Editor's Choice, back cover)

2. Yuan J, Liu L, Liu H*. Synergistic cuFe redox coupling over TiOx enables efficient CO-SCR DeNOx under chemical looping combustion flue gas conditions[J]. Separation and Purification Technology. 2026: 138770.

3. Guo K, Tang C, Cen L, Liu L, Liu H*, Sun Z. Bimetallic synergistic effect of chromium‑gallium nanoparticles on ZSM-5 framework for robust propane dehydrogenation[J]. Chemical engineering journal. 2026: 177346.

2025年

1. Liu H, Yuan J, Xie X, Peng J, Liu L, Zhao S, et al. Dehydrogenation dynamics of NH4+ intermediates direct N2 selectivity in high-temperature zeolite SCR[J]. Separation and Purification Technology. 2025: 136420.

2. Liu L, Deng L, Liu H, Sun Z. Synergy of bimetallic Pt and cu on CeO2 for reverse water-gas shift reaction to CO under equimolar H2/CO2 conditions[J]. Separation and Purification Technology. 2025: 136278.

3. Peng J, Zhao S, Liu H, Sun Z. Anti‑sulfur characteristic of Sm-doped FeMnCe catalyst for low-temperature denitration of flue gas[J]. Separation and Purification Technology. 2026: 137688.

4. Liu L, Deng L, Liu H, Sun Z. Realizing balanced performances of integrated CO2 capture and utilization over natural limestone with/without Ni modification in a lab-scale micro-fluidized bed reactor[J]. Journal of the Energy Institute. 2025: 102349.

5. Liu L, Wang H, Liu H, Sun Z. Attrition Characteristics of Ca-based Dual Functional Material in a Micro Fluidized-bed Reactor for Integrated CO2 Capture and Conversion[J]. Carbon Capture Science & Technology. 2025: 100531.

6. Wang H, Liu L, Liu H, Zhu X, Sun Z. Cooperative Enhancement of Ni/Ce-Fe-Mn-Ca Dual Functional Materials for Integrated CO2 Capture and Conversion to CO under Near-Equimolar H2/CO2 conditions[J]. Carbon Capture Science & Technology. 2025: 100520.

2024年：

1. Rongchang Cao, Lei Liu, Hanzi Liu*, Zhiqiang Sun*. Suppressing cyclic deactivation of magnesium-calcium dual-functional materials via dispersed metal-carbonate interfaces for integrated CO2 capture and conversion. Carbon Capture Science & Technology. 2024, 13, 100275. 

2. Hanzi Liu, Ling Cen, Xinlin Xie, Lei Liu, Zhao Sun, Zhiqiang Sun*.Engineering nanoparticle structure at synergistic Ru-Na interface for integrated CO2 capture and hydrogenation. Journal of Energy Chemistry. 2025, 100, 779-791.

3. Xinlin Xie, Lei Liu, Hanzi Liu*, Zhiqiang Sun*. Mechanistic insights into SO2-induced deactivation of Ni-based materials for integrated CO2 capture and methanation. Fuel. 2025, 382, 133755.

4. Junlin Peng, Xinlin Xie, Lei Liu, Hanzi Liu*, Zhiqiang Sun*.Enabling integrated CO2 capture and conversion over NiCe-modified calcite as cost-effective dual functional materials. Separation and Purification Technology. 2025, 363, 131919. 

5. Xiaopan Liu, Haonan Yu, Hanzi Liu*, Zhiqiang Sun*. Life cycle carbon footprint analysis of deep load regulation in coal-fired power plants based on machine learning: A case study of a 1000 MW unit in Hunan province. Case Studies in Thermal Engineering. 2025, 68, 105861.

6. Shilin Zhao, Yuxin Qian, Yuchen Wang, Qi Liu, Hanzi Liu*, Lidong Wang*, Zhiqiang Sun*, Catalytically enhanced adsorption of flue gas mercury by CuS modified iron or manganese oxides. Chemical Engineering Science. 2025, 313, 121727.

7. Hanzi Liu, Bingjie Liu, Xinlin Xie, Changfu You*, Haiming Wang*,Compositional engineering of NiFe catalysts on silica supports for efficient CO2 hydrogenation. Separation and Purification Technology. 2025, 370, 133172.

8. Xinlin Xie, Lei Liu, Hanzi Liu*, Zhiqiang Sun*. Calcium-based dual-functional materials for integrated CO2 capture and reverse water gas shift: Boosting stored CO2 hydrogenation via dispersed MgO-CaCO3 interfaces. Separation and Purification Technology. 2025, 371, 133384.

9. Liu, L.; Li, K.; Liu, H.; Sun, Z., A DFT-based kinetic equation for Co3O4 decomposition reaction in high-temperature thermochemical energy storage. Appl. Therm. Eng. 2025, 260.

10. Liu, L.; Li, K.; Liu, H.; Sun, Z., A DFT-based kinetic model for Cu-Al oxygen carrier material in chemical looping with oxygen uncoupling. Fuel 2025, 381.

11. Liu, L.; Xu, W.; Liu, H., Redox and melting characteristics of Mn-based ores for high-temperature thermochemical energy storage. Frontiers in Energy Research 2024, 12.

12. Liu, L.; Li, K.; Liu, H.; Sun, Z., DFT-based rate equation for thermochemical redox kinetics in a bubbling-fluidized bed reactor and its application to a manganese oxygen carrier in chemical looping. Proceedings of the Combustion Institute 2024, 40.

13. Zhao, S.; Wang, Y.; Xie, X.; Liu, X.; Liao, Y.; Liu, H.; Sun, Z., Adsorption mechanism of As2O3 on metal oxides (CaO, γ-Al2O3, α-Fe2O3): A density functional theory study. Appl. Surf. Sci. 2023, 641.

14. Zhao, S.; Wang, Y.; Xie, X.; Liu, Q.; Liu, X.; Liu, H.; Liao, Y.; Duan, Y.; Gupta, R.; Shen, A.; Sun, Z., Arsenic removal from coal-fired flue gas by MnO2 coated magnetic flower-like Fe3O4 composites: Experimental and DFT study. Chem. Eng. J. 2023, 478.

15. Sun, Z.; Hao, C.; Toan, S.; Zhang, R.; Li, H.; Wu, Y.; Liu, H.; Sun, Z., Recent advances in exsolved perovskite oxide construction: exsolution theory, modulation, challenges, and prospects. Journal of Materials Chemistry A 2023, 11, 17961-17976.

-2024年： 

1. Liu, H.; You, C.; Wang, H., Experimental and Density Functional Theory Studies on the Zeolite-Based Fe–Ni–W Trimetallic Catalyst for High-Temperature NOx Selective Catalytic Reduction: Identification of Active Sites Suppressing Ammonia Over-oxidation. ACS Catalysis. 2021, 11, 1189-1201.

2. Liu, H.; Zhang, Y.; Wang, H.; You, C., Performance of Fe-Ni-W exchanged zeolite for NOx reduction with NH3 in a lab-scale circulating fluidized bed. Fuel. 2022, 307, 121807. 

3. Liu, H.; You, C.; Wang, H., Time-resolved in-situ IR and DFT study: NH3 adsorption and redox cycle of acid site on vanadium-based catalysts for NO abatement via selective catalytic reduction. Chemical Engineering Journal. 2020, 382, 122756. 

4. Liu, H.; Chen, Z.; Wang, H.; You, C., Active centers response to SO2 and H2O poisoning over Fe-W-Ni exchanged zeolite for high-temperature NH3-SCR: Experimental and DFT Studies. Applied Surface Science. 2021, 570, 151105. 

5. Liu, H.; Zhao, S.; You, C.; Wang, H., Experimental Study of the Enhancement of the Selective Noncatalytic Reduction Denitrification Process with Methane and Propane in a Circulating Fluidized Bed. Industrial & Engineering Chemistry Research. 2019, 58, 7825-7833. 

6. Wang, T.; Liu, H.*; Sun, B., Catalytic conversion of NO assisted by plasma over Mn-Ce/ZSM5-multi-walled carbon nanotubes composites: Investigation of acidity, activity and stability of catalyst in the synergic system. Applied Surface Science. 2018, 457, 187-199. 

7. Liu, H.; Wang, T.; Sun, B., Influence of the TiO2/multi-walled carbon nanotubes (MWCNTs) mass ratio on NO removal over the Mn/TiO2(x)-MWCNTs(1−x) catalyst assisted by plasma. Reaction Kinetics Mechanisms and Catalysis. 2017, 121, 735-749. 

8. 刘涵子，王海名，由长福. 铁基分子筛高温NH3-SCR反应性能及机理研究. 工程热物理学报. 2022.

9. Wang, H.; Liu, H.; Chen, Z.; You, C., Interaction between SO2 and NO in their adsorption and photocatalytic conversion on TiO2, Chemosphere. 2020, 249, 126136.

10. Wang, T.; Liu, H.;  Sun, B., A plasma-assisted catalytic system for NO removal over CuCe/ZSM-5 catalysts at ambient temperature, Fuel Process. Technol. 2017, 158, 199-205.

11. Wang, T.; Liu, H.;  Sun, B., NO and SO2 Removal using Dielectric Barrier Discharge Plasma at Different Temperatures. J. Chem. Eng. Jpn. 2017, 50, 702-709.

12. Wang, T.; Liu, H.;  Sun, B., Effect of plasma-catalyst system on NO removal using M–Cu (M = Mn, Ce, Cr, Co, and Fe) catalysts. Jpn. J. Appl. Phys., 2016, 55, 116202. 

13. Wang, T.; Zhang, X.; Liu, H.;  Sun, B., A comparison of NO reduction over Mn–Cu/ZSM5 and Mn–Cu/MWCNTs catalysts assisted by plasma at ambient temperature. Catal. Surv. Asia, 2017, 21, 94-102. 

14. Chen, Z.; You, C.; Liu, H.; Wang, H., The synergetic particles collection in three different wet flue gas desulfurization towers: A pilot-scale experimental investigation, Fuel Process. Technol. 2018, 179, 344-350.

15. Wang, T.; Zhang, X.; Liu, J.; Liu, H.;  Sun, B., Comparison of NO conversion over Cu/M (M = TiO2, Al2O3, ZSM-5, carbon nanotubes, activated carbon) catalysts assisted by plasma, React. Kinet. Mech. Cat., 2018, 124, 587-601.

16. Wang, T.; Zhang, X.; Liu, J.; Liu, H.;  Sun, B., Effects of temperature on NOx removal with Mn-Cu/ZSM5 catalysts assisted by plasma. Appl. Therm. Eng. 2018, 130, 1224-1232.

17. Wang, T.; Zhang, X.; Liu, J.; Liu, H.;  Sun, B., Plasma-assisted catalytic conversion of NO over Cu-Fe catalysts supported on ZSM-5 and carbon nanotubes at low temperature, Fuel Process. Technol., 2018, 178, 53-61.

18. Dai, X.; Zhou, X.; Liu, H.; Wang, T.; Zhang, Y.; Zhang, H.; Sun, B., Molecular-level insights into the immobilization of vapor-phase mercury on Fe/Co/Ni-doped hierarchical molybdenum selenide. Journal of Hazardous Materials 2021, 420, 126583.

19. Gu, S.; Yang, Z.; Chen, Z.; Wang, H.; Liu, H.; Zhang, W.; You, C., Insights into the desulfurization mechanism of low-grade limestone as absorbent induced by particle size. Fuel 2021, 305, 121444.

教育经历

1. 2018.09~2022.06

清华大学  |  动力工程及工程热物理  |  工学博士

2. 2015.09~2018.03

华北电力大学（北京）  |  热能工程  |  工学硕士

3. 2011.09~2015.06

华北电力大学（北京）  |  热能与动力工程  |  工学学士  

专利成果

1. 刘涵子, 由长福. 一种用于中高温脱硝的铁基催化剂及其制备方法和应用. 发明专利. 201910523584.3. 

2. 刘涵子, 由长福. 一种SNCR增效剂制备方法和应用. 发明专利. 202111020701.8.

3. 由长福, 刘涵子. 一种500-900度脱硝增效方法. 发明专利, 202011081409.2.

4. 由长福, 刘涵子. 一种循环流化床锅炉脱硝增效添加剂制备方法. 发明专利. 202011106373.9.

5. 王海名，刘涵子，由长福. 一种水泥窑装置和SNCR脱硝方法. 发明专利.  202110191347.9.

学术兼职

Energy & Environment Nexus青年编委；《Atmosphere》期刊 Guest Editor