Photocatalytic intermolecular anti-Markovnikov hydroamination of unactivated alkenes with N-hydroxyphthalimide
发布时间：2021-07-02
点击次数：
DOI码：10.1039/D0QO01321H
发表刊物：Organic Chemistry Frontiers
摘要：A visible-light-induced/phosphite-promoted anti-Markovnikov hydroamination of alkenes with N-hydroxyphthalimide was successfully realized, which was initiated by a proton-coupled electron transfer to enable direct cleavage of its N–O bond. Both experimental and computational studies were performed to probe the reaction mechanism. A wide range of alkenes, including vinyl ethers, silanes, and sulfides as well as electronically unbiased terminal and internal alkenes, were well tolerated in this hydroamination protocol.
合写作者：Yuan-Zhuo Hu
第一作者：Zhi-Peng Ye
论文类型：期刊论文
通讯作者：Peng-Ju Xia*, Kai Chen*, Hao-Yue Xiang*, Hua Yang*
卷号：8
期号：2
页面范围：273-277
是否译文：否
发表时间：2020-11-09
收录刊物：SCI
发布期刊链接：https://pubs.rsc.org/en/content/articlelanding/2020/qo/d0qo01321h/unauth#!divAbstract