Thermal treatment and ammoniacal leaching for the recovery of valuable metals from spent lithium-ion batteries
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- 影响因子：5.448
- DOI码：10.1016/j.wasman.2018.02.024
- 发表刊物：WASTE MANAGEMENT
- 关键字：Spent Li-ion batteries, Cathode active powder, Thermal treatment, Ammoniacal leaching, Double salts
- 摘要：The recycling of spent commercial lithium-ion batteries (LIBs) generates numerous environmental and economic benefits. In this research, a thermal treatment-ammoniacal leaching process is proposed to recover valuable metals from cathode active powder. Based on the thermal behavior by TG-DSC analysis, the cathode active powder is calcined at 300 degrees C and 550 degrees C in air atmosphere, and the crystalline phase characterization indicates that a new phase of Co3O4 appears in the cathode active powder calcined at 550 degrees C, which signifies that the layer structure of LiCoO2 collapses. The valence of manganese increases to form Li4Mn3O12 in spinel structure of LiMn2O4. Using calcined cathode powder as feed material, ammoniacal leaching is carried out in (NH4)(2)SO4-(NH4)(2)SO3 solution. Under the optimum conditions, Ni, Co, Mn and Li can be completely leached out with efficiencies of 98%, 81%, 92% and 98%, respectively. However, with the increase of ammonia concentration, the leaching efficiency of Mn decreases dramatically to 4% due to the formation of double salts. It is found that Co and Mn can be precipitated into residues in the form of (NH4)(2)Co(SO4)2 center dot H2O, (NH4)(2)Mn(SO3)(2)center dot H2O and (NH4)(2)Mn(SO4)(2)center dot 6H(2)O under different leaching parameters. Based on the corresponding relationship between the leaching efficiency and phase evolution of object element, selective leaching can be achieved by controlling the formation of double salts. (C) 2018 Elsevier Ltd. All rights reserved.
- 论文类型：期刊论文
- 学科门类：工学
- 一级学科：冶金工程
- 文献类型：J
- 卷号：75
- 页面范围：469-476
- 是否译文：否
- 发表时间：2018-03-02
- 收录刊物：SCI
附件：
1-s2.0-S0956053X18300904-main04.pdf
