文青波

博士生导师 硕士生导师

所在单位:粉末冶金研究院

学历:博士研究生毕业

办公地点:中南大学本部校区三一大楼617

性别:男

联系方式:wentsingbo@csu.edu.cn

学位:工学博士学位

在职信息:在职

毕业院校:达姆施塔特工业大学(德国)

学科:材料科学与工程

曾获荣誉:

2018-03-05  当选:  玛丽居里优秀研究计划奖

2011-05-31  当选:  桑德环境奖学金优秀论文特等奖

2010-11-30  当选:  湖南大学长江环境奖学金

2009-05-31  当选:  湖南省优秀大学毕业生

2008-11-30  当选:  国家奖学金

2007-11-30  当选:  国家奖学金

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Single-source-precursor synthesis of dense SiC/HfCxN1-x-based ultrahigh-temperature ceramic nanocomposites

发布时间:2021-09-04

点击次数:

影响因子:7.79

发表刊物:Nanoscale

摘要:A novel single-source precursor was synthesized by the reaction of an allyl hydrido polycarbosilane (SMP10) and tetrakis(dimethylamido)hafnium(IV) (TDMAH) for the purpose of preparing dense monolithic SiC/HfCxN1−x-based ultrahigh temperature ceramic nanocomposites. The materials obtained at different stages of the synthesis process were characterized via Fourier transform infrared (FT-IR) as well as nuclear magnetic resonance (NMR) spectroscopy. The polymer-to-ceramic transformation was investigated by means of MAS NMR and FT-IR spectroscopy as well as thermogravimetric analysis (TGA) coupled with in situ mass spectrometry. Moreover, the microstructural evolution of the synthesized SiHfCN-based ceramics annealed at different temperatures ranging from 1300 °C to 1800 °C was characterized by elemental analysis, X-ray diffraction, Raman spectroscopy and transmission electron microscopy (TEM). Based on its high temperature behavior, the amorphous SiHfCN-based ceramic powder was used to prepare monolithic SiC/HfCxN1−x-based nanocomposites using the spark plasma sintering (SPS) technique. The results showed that dense monolithic SiC/HfCxN1−x-based nanocomposites with low open porosity (0.74 vol%) can be prepared successfully from single-source precursors. The average grain size of both HfC0.83N0.17 and SiC phases was found to be less than 100 nm after SPS processing owing to a unique microstructure: HfC0.83N0.17 grains were embedded homogeneously in a β-SiC matrix and encapsulated by in situ formed carbon layers which acted as a diffusion barrier to suppress grain growth. The segregated Hf-carbonitride grains significantly influenced the electrical conductivity of the SPS processed monolithic samples. While Hf-free polymer-derived SiC showed an electrical conductivity of ca. 1.8 S cm−1, the electrical conductivity of the Hf-containing material was analyzed to be ca. 136.2 S cm−1.

合写作者:Yeping Xu, Binbin Xu, Claudia Fasel, Olivier Guillon, Buntkowsky Gerd, Emanuel Ionescu, Ralf Riedel

第一作者:Qingbo Wen

论文类型:期刊论文

通讯作者:Zhaoju Yu

文献类型:J

卷号:6

期号:22

页面范围:13678-13689

是否译文:

发表时间:2014-11-01

收录刊物:SCI

发布期刊链接:https://pubs.rsc.org/en/content/articlelanding/2014/nr/c4nr03376k/unauth

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