Synthesis of Alkali Metals Functionalized Porous Carbon for Enhanced Selective Adsorption of Carbon Dioxide: A Theoretically Guided Study
发布时间：2024-09-30
点击次数：
DOI码：10.1021/acs.energyfuels.1c02313
所属单位：中南大学
发表刊物：Energy and Fuels
关键字：Adsorption, Alkali metals, Carbon, Doping, Selectivity
摘要：Developing an adsorbent with high adsorption capacity and high selectivity is of great importance for the post-combustion CO2capture. Inspired by the theoretical calculation findings that the introduction of alkali metal atoms (e.g., Li, Na, and K) into the carbon framework can significantly increase the CO2adsorption capacity through the enhanced electrostatic interaction, herein, we have successfully developed a series of alkali metal doped carbons through a simple and effective strategy. The systematic characterization results prove that alkali metals are uniformly introduced into the carbon framework without changing the pore size distribution and amorphous structure of the original material, but slightly reducing the specific surface area. The adsorption performances from the static adsorption and the dynamic breakthrough experiments with a binary mixture of CO2/N2(15/85, v/v) reveal that the doping of alkali metals can greatly enhance the capture and separation of CO2, in which the lithium-doped porous carbon presents the best CO2uptake of 4.1 mmol/g at 25 °C (48.3% higher than that of undoped carbon) with the highest CO2/N2selectivity of 47 and fastest adsorption rate. The high adsorption capacity and selectivity presented are comparable to the data reported in the previous literature. The density functional theory and grand canonical Monte Carlo molecular simulation results demonstrate that, compared with N2, alkali metal doped carbon has a stronger binding energy and higher adsorption density for CO2and thus increases the CO2/N2selectivity to a greater extent. This proof-of-concept work paves an alternative way for the development of high-performance CO2adsorbents.
论文类型：期刊论文
卷号：35
期号：19
页面范围：15962 - 15968
ISSN号：08870624
是否译文：否
发表时间：2021-10-07
收录刊物：SCI
发布期刊链接：https://pubs.acs.org/doi/10.1021/acs.energyfuels.1c02313