陈智慧

Journal Publications

Highly Efficient Multiphoton Absorption of Zn-AIEgen Frameworks
  • Release time:2021-12-28
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  • Impact Factor:15.336
  • Journal:Angew. Chem. Int. Ed.
  • Abstract:A series of luminescent frameworks was synthesized from the selective combination of aggregation induced emission (AIE)-linker tetra-(4-carboxylphenyl)ethylene (H4TCPE) and Zn2+. Complex 1 was formed by the close packing of Zn-TCPE hinge, and isostructural complexes 2–5 were constructed by the linkage of Zn-TCPE layer and pillar ligands. These complexes exhibit highly efficient multiphoton excited photoluminescence (MEPL) and concomitant third-harmonic generation (THG). The multiphoton absorption (MPA) parameters of 1 are superior to other multiphoton emission materials including the perovskite nanocrystals. The incorporation of pillar linkers slows down the charge transfer between layers of Zn-TCPE, and the aromatic core of pillar linkers has a great influence on the MPA performance of the corresponding frameworks.
  • Co-author:Fan Wenxuan, Su Jie, Lin Tingting, Xiao Si, Meng Jianqiao, He Jun
  • First Author:Liu Naifang#, Chen Zhihui#
  • Indexed by:Journal paper
  • Correspondence Author:Jagadese J. Vittal*, Jiang Jianzhuang*
  • Document Code:e202115205
  • Discipline:Natural Science
  • First-Level Discipline:Chemistry
  • Document Type:J
  • Volume:61
  • Translation or Not:no
  • Date of Publication:2021-12-28
  • Included Journals:SCI