中南大学 liuchao

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Journal Publications

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[1]Dang-Dang Ding, Lan-Yan Li, Xin-Yu Chen, Jun Yan and Chao Liu*, Controlled Topological Reorganization in Cu–Ag Nanoclusters for Selective Electrocatalytic CO2 Reduction to Ethanol, 2026, Submitted.
[2]Xin-Yu Chen, Ya-Qi Li, Xin-Yu Bai, Dang-Dang Ding, Xin-Yan Chi, Wei-Qiang Zhang, Jun Yan, Tian-Fu Liu, Yong Pei, and Chao Liu,* Structural Fusion-Induced Activity Suppression in Copper Nanoclusters for Electrocatalytic Nitrate Reduction, 2025, Submitted.
[3]Qian Han, Xinyu Chen, Xuan Peng, Ziyan Zhang, Yilong He, Zheyuan Zhou, Chao Liu,* Zhuxin Dong, * Ligand-Engineered Cu13 Nanoclusters Direct Distinct Programmed Cell Death Pathways for Tumor-Selective Therapy, 2025, Submitted.
[4]Qian Han, Xiao-Wei Wang, Hong-Yan Zhu, Lan-Yan Li, Wei-Dong Yu and Chao Liu*，Precise Anchoring of Ag+ Sites on a Thiacalix[4]arene-Stabilized Titanium-oxo Cluster for Efficient CO2-to-CO Electroreduction, CrystEngComm, 2025, Accepted.
[5]Hong-Yan Zhu, Xiao-Wei Wang, Xin-Yu Chen, Lan-Yan Li, Yi-Xin Li, Wei Dong Yu, Jun Yan, and Chao Liu*, Dynamic Structural Engineering of Ferrocene-Functionalized Ag20 Nanoclusters for Enhanced CO2 Electroreduction Performance, Chemical Science, 2025, DOI: 10.1039/D5SC06306J.
[6]Xin-Yu Chen, Lan-Yan Li, Lan-Cheng Zhao, Qing-Yi Liu, Dang-Dang Ding, Li-Kai Wang, Hong-Bing Mo, Jun Yan, Chao Liu*，Ag+-Mediated Structural Reconstruction of a Metastable Cu35 Cluster Toward Cu–Ag Heterometallic Architectures for Superior Electrocatalytic CO2-to-Ethanol Conversion, Angew. Chem. Int. Ed, 2025, e202511232.
[7]Hao-Nan Zhou, Lan-Yan Li, Yi-Xin Li, Hong-Bing Mo,* Jun Yan, Chao Liu*, Ligand-Engineered Octanuclear Bismuth-Oxo Clusters with Exposed Active Sites for Enhanced CO2-to-HCOOH Electroreduction, Chinese Chemical Letters, 2025,15, 111269.
[8]Ru-Xin Meng, Cheng-Lan Zhao, Pan-Li Luo, Yi-Qi Tian, Qing Tang,* Li-Kai Wang,* Jun Yan, Chao Liu,* Atomic-Level Engineering of Single-Atom Silver Site Distribution on Titanium-Oxo Cluster to Boost CO2 Electroreduction, Chemical Science, 2025, 16, 6845-6852.
[9]Hao-Nan Zhou, Qing-Yi Liu, Lan-Yan Li,* Jun Yan, Chao Liu,* In-situ Oxidation Ring-Opening of Calix[8]arene for Constructing Stable Bismuth-oxo Clusters with Exposed Catalytic Sites: Efficient Catalysts for Specific CO2-to-HCOOH Electroreduction, 2024, Inorganic Chemistry, 2024, 63, 20501–20509.
[10]Wen-Lei Mu, Lan-Yan Li, Xu-Zi Cong, Peng-Kun Xia, Xin-Yu Chen, Qing-Yi Liu, Li-Kai Wang*, Jun Yan*, Chao Liu*，Hierarchical Assembly of High-Nuclearity Copper(I) Alkynide Nanoclusters: Highly Effective CO2 Electroreduction Catalyst towards Hydrocarbons, J. Am. Chem. Soc, 2024, 146, 28131–28140.
[11]Xin-Yu Chen, Qing-Yi Liu, Wei-Dong Yu, Jun Yan, Chao Liu,* Advancements in Calixarene-Protected Titanium-Oxo Clusters: From Structural Assembly to Catalytic Functionality, Chemical Communication, 2024, 60, 11890-11898 (Feature Article, Invited ).
[12]Shang-Qian Li, Qing-Yi Liu, Lan-Yan Li, Kai-Yu Liu, Jun Yan, Chao Liu,* Thiacalix[4]arene-Stabilized Sb/Ag Bimetallic Nanoclusters: Elucidating the Effects of Sb Doping on Electrocatalytic CO2 Reduction in Ag clusters, Inorganic Chemistry, 2024, 63, 18972-18980.
[13]Wen-Lei Mu, Yu-Ting Luo, Peng-Kun Xia, Yong-Lei Jia, Pu Wang, Yong Pei,* Chao Liu*，Atomically Precise Mo2Cu17 Bimetallic Nanocluster: Synergistic Mo2O4-Coupled Copper Alkynyl Cluster for Improved Hydrogen Evolution Reaction Performance, Inorganic Chemistry. 2024, 63, 6767–6775
[14]Liang-Jun Li, Wen-Lei Mu, Yi-Qi Tian, Wei-Dong Yu*, Lan-Yan Li*, Jun Yan, and Chao Liu*, Ag1+ Incorporation via Zr4+-Anchored Metalloligand: Fine-Tuning the Single-Atom Catalytic Ag Sites in Zr/Ag Bimetallic Clusters for Enhanced eCO2RR-to-CO activity, Chemical Science, 2024, 15, 7643-7650.
[15]Yin Zhang, Wei-Dong Yu,* Fang-Qian Wang, Xiang-Nan Wang, Jia-Wan Zhou, Chao Liu,* and Jun Yan*, Terpyridine complexes based polyoxometalates with [W10O32]4- anions as high-efficiency dual-site catalysis for thioether oxidation reaction, Chinese Journal of Chemistry, 2024, 42, 592-598.
[16]Yi-Qi Tian, Lin-Fang Dai, Wen-Lei Mu, Wei-Dong Yu, Jun Yan*, Chao Liu*，Atomically Accurate Site-Specific Ligand Tailoring of Highly Acid- and Alkali-Resistant Ti(IV)-based Metallamacrocycle for Enhanced CO2 Photoreduction, Chemical Science, 2023, 14, 14280-14289.
[17]Er-Meng Han, Ru-Xin Meng, Yi-Qi Tian, Jun Yan, Kai-Yu Liu,* Chao Liu*，Al12Co4: A Pioneering Heterometallic Aluminum-Oxo Cluster with Exposed Co(II) Sites for Oxygen Evolution Reaction, Chemical Communication. 2023, 59, 11097-11100.
[18]Shang-Qian Li, Yi-Qi Tian, Liang Jun Li, Wen-Lei Mu, Ru-Xin Meng, Jun Yan* and Chao Liu,* Synthesis and Characterization of Ag(I) Alkynyl Nanoclusters Utilizing MoVI-Anchored Thiacalix[4]arene Metalloligands: Application in Electrocatalytic CO2 Reduction, 2023, Polyoxometalates, 2024, 3(1): 9140038.
[19]Liang-Jun Li, Yu-Ting Luo, Yi-Qi Tian, Pu Wang,* Xiao-Yi Yi, Jun Yan, Yong Pei,* and Chao Liu*，Unveiling the Remarkable Stability and Catalytic Activity of a 6-Electron Superatomic Ag30 Nanocluster for CO2 Electroreduction, Inorganic Chemistry, 2023, 62, 14377–14384.
[20]Yi-Qi Tian, Wen-Lei Mu, Lin-Lin Wu,* Xiao-Yi Yi, Jun Yan* and Chao Liu* , Stepwise assembly of thiacalix[4]arene-protected Ag/Ti bimetallic nanoclusters: Accurate identification of catalytic Ag sites in CO2 electroreduction, Chemical Science, 2023, 14, 10212-10218.

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