Yi-Qi Tian, Er-Meng Han, Bo Wan, Wei-Dong Yu, Ming-Zhao Chen, Jun Yan, Xiao-Yi Yi, Chao Liu*，Heterometallic Polyoxotitanium Cluster as Bifunctional Electrocatalyst for Overall Water Splitting
发布时间：2022-05-19
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发表刊物：Inorganic Chemistry, 2022, 61, 10151–10158.
摘要：我们首次系统研究了金属掺杂钛氧簇作为双功能电催化剂的电解水分解性能。在溶剂热条件下将丁二酮肟，吡嗪二羧酸配体与Ti4+, Co2+共同组装，得到了一例梯形状的双金属簇{Ti10Co2}。我们利用质谱详细研究该簇的组装机制，此外，将{Ti10Co2}分散到碳布上制备出来的工作电极在OER和HER中均表现出了良好的电催化活性和循环性能。将其作为双电极构建的两电极体系在水分解反应中，在1.67V时可以达到10 mA/cm-2的电流密度。
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上一条： Shang-Qian Li, Lin-Fang Dai, Yi-Qi Tian, Yi-Xiao Yi, Jun Yan and Chao Liu,* Polymolybdate-Guided Assembly of a Thiacalix[4]arene Protected Ag Nanocluster for Electrocatalytic CO2 Reduction, Chemical Communication, 2023,59, 575-578.
下一条： Yi-Qi Tian, Yun-Shu Cui, Jia Hui-Zhu, Cong-Qiao Xu*, Xiao-Yi Yi, Jun Li and Chao Liu*, Ancillary ligands-regulated Ti(IV)-based metallocalixarene coordination cages for photocatalytic H2 evolution, Chemical Communication, 2022, 58, 9034-9037.