Function mechanism of CO-CO2 atmosphere on the formation of Na2SnO3 from SnO2 and Na2CO3 during the roasting process
发布时间:2016-07-05
点击次数:
所属单位:School of Minerals Processing & Bioengineering, Central South University
发表刊物:Powder Technology
关键字:SnO2; Na2SnO3; Roasting; CO-CO2 atmosphere; Function mechanism
摘要:High-purity Na2SnO3 product has been successfully prepared from SnO2 and Na2CO3 via a novel process developed by the authors' group. This study proposed a function mechanism of CO-CO2 atmosphere on the formation of Na2SnO3 in the roasting process using SEM-EDS, micro-region XRD and FTIR analyses. The results showed that under 5 vol%–20 vol% CO/(CO + CO2) atmosphere, the main reactions in the SnO2-Na2CO3 system included Na2CO3 = Na2O + CO2 and Na2O + SnO2 = Na2SnO3. The reactions were affected by the CO2 partial pressure as well as by the CO content in the CO-CO2 atmosphere.
论文类型:基础研究
学科门类:冶金工程学
文献类型:J
卷号:301
期号:2016
页面范围:102-109
是否译文:否
发表时间:2016-05-25
发布期刊链接:http://www.sciencedirect.com/science/article/pii/S0032591016302893
附件:
Function mechanism of CO-CO2 atmosphere on the formation of Na2SnO3.pdf