Journal:Chemical Communication, 2022, 58, 6028-6031.

Abstract:以叔丁基杯[4]芳烃为配体制备了第一例钛(IV)基金属杯芳烃纳米笼簇，该团簇用六个疏水的杯芳烃分子将一个[Ti13O14]笼保护。实验表明，该团簇在高浓度酸/碱溶液中表现出超稳定性；理论计算证明强的Ti(IV)-O键相互作用和大的溶剂化能是该团簇具有超稳定性的原因。因为强的稳定性及良好的光响应活性，该团簇将其作为光催化剂催化胺氧化成亚胺表现出了高的选择性和循环稳定性。

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